Dyers task is
to give a visual impression to the human eye. The eye is a very positive organ
that can detect very slight color differences. Since dyes are industrial
products, they may contain impurities and colored or colorless by products,
depending on their production process. Dyes are standardized not to a certain
chemical composition but to a defined coloristic value. Consequently they may
be composed of mixture of dyes and may contain shading components. For example
all disperse and cationic blacks are mixtures of dyes.
Principles of
standardization setup by special of dye producer as testing procedure for
textile dyes.
a. Relative
color strength in solution.
b. Relative
color strength and residual color difference by reflectance measurements.
c. Solubility
and solution stability.
d. Electrolyte
stability of reactive dyes.
e. Viscosity of
liquid dyes.
f. Dispersion
behavior and dispersion properties.
The coloring
properties of a dye assessed by preparing a dyed test sample whose color is
evaluated. This must a principle always be done by the human eye because color
perception being a objective sense impression, is not accessible to direct
measurement. However, the aid of colorimetry this visual perception can be
represented more or less cloyety by measurable quantities.
To test a dye
dyed test a dye dyed test specimen from bath the sample dye and the standard
are compared under conditions that are as identical as possible and assessed
visually or colorimetrically and then calculated in relative terms to the
standard. A widely used method to calculate color strength is a determination
based on the weighted sum of k/s values (k is the coefficient of absorption, s
is the coefficient of scatter which is used in standard specifications.
For the dyeing
process in aqueous liquor the dye must have adequate solubility or
dispersibility. In general good solubility is necessary for good application
properties. If the solubility is poor, local coloration (specks) spots uneven
effects and poor fastness can be produced.
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